Asymmetric Baeyer-Villiger oxidation of cyclic ketones with hydrogen peroxide mediated by a series of new chiral Pt(II) complexes afforded lactone products in good yields and moderate enantioselectivities.
Tailoring Pt(II) Chiral Catalyst Design for Asymmetric Baeyer-Villiger Oxidation of Cyclic Ketones with Hydrogen Peroxide
SCARSO, Alessandro;STRUKUL, Giorgio
2006-01-01
Abstract
Asymmetric Baeyer-Villiger oxidation of cyclic ketones with hydrogen peroxide mediated by a series of new chiral Pt(II) complexes afforded lactone products in good yields and moderate enantioselectivities.
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