Cyclocarbonylation reactions of a series of enediynes, promoted by pentacarbonyliron, proceed selectively on the diyne, resulting in the formation of cyclopentadienone-iron tricarbonyl complexes, without competing enyne cyclocarbonylation.
Selectivity in the pentacarbonyliron-promoted cyclocarbonylation of enediynes
PEROSA, Alvise
1995-01-01
Abstract
Cyclocarbonylation reactions of a series of enediynes, promoted by pentacarbonyliron, proceed selectively on the diyne, resulting in the formation of cyclopentadienone-iron tricarbonyl complexes, without competing enyne cyclocarbonylation.
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