Homogeneous catalysis is witnessing a radical change in perspective, with an increasing awareness that a clear understanding of the nanometric tridimensional space where the reactions take place plays a key role in controlling both the activity and even more importantly the different selectivities of chemical transformations. The understanding of what happens at this level during a catalytic process can spur further achievements in deciphering biological phenomena such as enzyme activity. Supramolecular interactions are currently considered in homogeneous catalytic reactions, and a better definition of the nano‐space around the active site is the target for developing more active and selective systems.
Resorcin[4]arene Hexamer: From Nanocontainer to Nanocatalyst
Strukul Giorgio;Fabris Fabrizio;Scarso Alessandro
2022-01-01
Abstract
Homogeneous catalysis is witnessing a radical change in perspective, with an increasing awareness that a clear understanding of the nanometric tridimensional space where the reactions take place plays a key role in controlling both the activity and even more importantly the different selectivities of chemical transformations. The understanding of what happens at this level during a catalytic process can spur further achievements in deciphering biological phenomena such as enzyme activity. Supramolecular interactions are currently considered in homogeneous catalytic reactions, and a better definition of the nano‐space around the active site is the target for developing more active and selective systems.File | Dimensione | Formato | |
---|---|---|---|
2022 Wiley book hexamer Chapt 24 good.pdf
Open Access dal 30/03/2024
Tipologia:
Documento in Post-print
Licenza:
Accesso gratuito (solo visione)
Dimensione
802.28 kB
Formato
Adobe PDF
|
802.28 kB | Adobe PDF | Visualizza/Apri |
I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.