The oxidation of olefins with hydrogen peroxide catalyzed by a Pt(II)/M bimetallic system is reported where M = Rh, Ir, Pd complexes. While with the former two metals no oxidation is obtained, with (dppe)Pd(CF3)(solv)+ the reaction selectively produces ketones. This appears to be a genuine example of bifunctional catalysis. © 1990 Academic Press Inc.
USE OF BIMETALLIC SYSTEMS FOR THE SELECTIVE OXIDATION OF OLEFINS WITH HYDROGEN-PEROXIDE
STRUKUL, Giorgio;PINNA, Francesco
1990-01-01
Abstract
The oxidation of olefins with hydrogen peroxide catalyzed by a Pt(II)/M bimetallic system is reported where M = Rh, Ir, Pd complexes. While with the former two metals no oxidation is obtained, with (dppe)Pd(CF3)(solv)+ the reaction selectively produces ketones. This appears to be a genuine example of bifunctional catalysis. © 1990 Academic Press Inc.
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