The oxidation of olefins with hydrogen peroxide catalyzed by a Pt(II)/M bimetallic system is reported where M = Rh, Ir, Pd complexes. While with the former two metals no oxidation is obtained, with (dppe)Pd(CF3)(solv)+ the reaction selectively produces ketones. This appears to be a genuine example of bifunctional catalysis. © 1990 Academic Press Inc.

USE OF BIMETALLIC SYSTEMS FOR THE SELECTIVE OXIDATION OF OLEFINS WITH HYDROGEN-PEROXIDE

STRUKUL, Giorgio;PINNA, Francesco
1990-01-01

Abstract

The oxidation of olefins with hydrogen peroxide catalyzed by a Pt(II)/M bimetallic system is reported where M = Rh, Ir, Pd complexes. While with the former two metals no oxidation is obtained, with (dppe)Pd(CF3)(solv)+ the reaction selectively produces ketones. This appears to be a genuine example of bifunctional catalysis. © 1990 Academic Press Inc.
1990
Studies in Surface Science and Catalysis
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/30836
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