Ethanol steam reforming has been investigated in the low temperature range, focusing not only on H2pro-ductivity, but also on catalyst stability, very critical parameters under such conditions. Different supports(SiO2and ZrO2), active phases (Ni, Co, Cu) and reaction temperature (300–500◦C) have been employed.Ni confirmed the best performing active phase to promote ethanol decomposition and reforming alreadyat low reaction temperature. However, stability towards coking remains a key problem. The supportplays a key role from this point of view. Indeed, the stabilization of the active phase in very dispersedform allowed to reach stable catalyst performance with time-on-stream. SiO2, thanks to no Lewis acidityand sufficiently strong metal–support interaction, demonstrated an interesting support for Ni under theselected operating conditions

Silica and zirconia supported catalysts for the low-temperature ethanol steam reforming

NICHELE, Valentina;SIGNORETTO, Michela;
2014-01-01

Abstract

Ethanol steam reforming has been investigated in the low temperature range, focusing not only on H2pro-ductivity, but also on catalyst stability, very critical parameters under such conditions. Different supports(SiO2and ZrO2), active phases (Ni, Co, Cu) and reaction temperature (300–500◦C) have been employed.Ni confirmed the best performing active phase to promote ethanol decomposition and reforming alreadyat low reaction temperature. However, stability towards coking remains a key problem. The supportplays a key role from this point of view. Indeed, the stabilization of the active phase in very dispersedform allowed to reach stable catalyst performance with time-on-stream. SiO2, thanks to no Lewis acidityand sufficiently strong metal–support interaction, demonstrated an interesting support for Ni under theselected operating conditions
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/39688
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