Novel complexes between methyltrioxorhenium (MTO) and bis(fluorous- ponytailed) 2,2′bipyridines (bpy-Fn) were synthesized and used for the oxidation of alkenes with hydrogen peroxide under fluorous catalysis. High conversions and yields of the corresponding epoxides were obtained. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
An efficient and selective epoxidation of olefins with novel methyltrioxorhenium/(fluorous ponytailed) 2,2′-bipyridine catalysts
CRESTINI, Claudia
2010-01-01
Abstract
Novel complexes between methyltrioxorhenium (MTO) and bis(fluorous- ponytailed) 2,2′bipyridines (bpy-Fn) were synthesized and used for the oxidation of alkenes with hydrogen peroxide under fluorous catalysis. High conversions and yields of the corresponding epoxides were obtained. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
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