The isomerization of epoxides to the corresponding carbonyl compounds is efficiently catalyzed by the supramolecular organic nano-capsule formed by the self-assembly of six resorcin[4]arene units. The capsule provides a combination of weak Brønsted acidity and a suitable nano-environment that favors the metal-free isomerization reaction

The isomerization of epoxides to the corresponding carbonyl compounds is efficiently catalyzed by the supramolecular organic nano-capsule formed by the self-assembly of six resorcin[4] arene units. The capsule provides a combination of weak Bronsted acidity and a suitable nano-environment that favors the metal-free isomerization reaction.

Efficient epoxide isomerization within a self-assembled hexameric organic capsule

CANEVA, THOMAS;SPERNI, Laura;STRUKUL, Giorgio;SCARSO, Alessandro
2016-01-01

Abstract

The isomerization of epoxides to the corresponding carbonyl compounds is efficiently catalyzed by the supramolecular organic nano-capsule formed by the self-assembly of six resorcin[4] arene units. The capsule provides a combination of weak Bronsted acidity and a suitable nano-environment that favors the metal-free isomerization reaction.
2016
6
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/3677765
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