Melt-phase nucleophilic ring-opening polymerisation of macrocyclic aromatic ethers and thioethers at high temperatures within the cylindrical pores of an anodicalumina membrane, followed by dissolution of the template, enables replication of the membrane’s internal pore structure and so affords high-performance aromatic polymers with well-defined fibrillar or tubular morphologies.
Microfabrication of high-performance aromatic polymers as nanotubes or fibrils by in situ ring-opening polymerisation of macrocyclic precursors
ARICO', Fabio;
2003-01-01
Abstract
Melt-phase nucleophilic ring-opening polymerisation of macrocyclic aromatic ethers and thioethers at high temperatures within the cylindrical pores of an anodicalumina membrane, followed by dissolution of the template, enables replication of the membrane’s internal pore structure and so affords high-performance aromatic polymers with well-defined fibrillar or tubular morphologies.
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