PdCl2(PPh3)2 catalyzes the carbonylation of RNHN:NR (R = Ph, p-MeC6H4, p-FC6H4, p-ClC6H4) to give 50% RNHCOR. The mechanism is discussed.
Metals in organic syntheses. IV. A novel catalytic carbonylation reaction: the synthesis of arylamides from 1,3-diaryltriazenes in the presence of PdCl2(PPh3)2 as catalyst precursor
TONIOLO, Luigi
1979-01-01
Abstract
PdCl2(PPh3)2 catalyzes the carbonylation of RNHN:NR (R = Ph, p-MeC6H4, p-FC6H4, p-ClC6H4) to give 50% RNHCOR. The mechanism is discussed.
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