An imine-linked (+)-syn-benzotricamphor derivative gives access to chiral unimolecular cages exhibiting internal cavities of new shapes and volumes. One of these hosts hydrocarbon gases at low temperatures in solution through CH−π attractive interactions. No encapsulation is observed when the cage structure is too narrow or too large for the guest

Gases as Guests in Benzocyclotrimer Cage Hosts

SCARSO, Alessandro;DE LUCCHI, Ottorino;FABRIS, Fabrizio
2009-01-01

Abstract

An imine-linked (+)-syn-benzotricamphor derivative gives access to chiral unimolecular cages exhibiting internal cavities of new shapes and volumes. One of these hosts hydrocarbon gases at low temperatures in solution through CH−π attractive interactions. No encapsulation is observed when the cage structure is too narrow or too large for the guest
2009
11
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/22230
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